Memory Kernels and Fluctuation-Dissipation Relations far from Equilibrium

Friederike Schmid (U Mainz)

Jun 24. 2021, 16:30 — 17:00

We consider memory effects in two examples of colloidal dispersions
 far from equilibrium: A driven colloid that is pulled by an external
 force through a Lennard-Jones fluid, and a colloid immersed in a bath
 of active Brownian particles. These systems are mapped to an implicit
 solvent model containing colloids only, and the effective dynamical
 equation takes the form of a Generalized Langevin Equation (GLE).  The
 nonequilibrium driving force have a profound effect on the amplitude
 and shape of memory kernels. The first fluctuation dissipation
 relation, which relates the non-equilibrium response of the system to
 a perturbation with the stationary correlation functions, breaks down
 far from equilibrium.  Nevertheless, the second fluctuation
 dissipation theorem that relates the noise fluctuations and the memory
 kernel is always strictly fulfilled. 
 
 We present a mathematical argument why this generally holds for memory
 kernels that are reconstructed from a deterministic Volterra equation
 for correlation functions, even for non-stationary, non-Hamiltonian,
 non-equilibrium systems. We also discuss the relation to the 
 corresponding result from the Mori-Zwanzig formalism for Hamiltonian
 systems.

Further Information
Venue:
ESI Boltzmann Lecture Hall
Associated Event:
Memory Effects in Dynamical Processes: Theory and Computational Implementation (Online Workshop)
Organizer(s):
Christoph Dellago (U of Vienna)
Anja Kuhnhold (U of Freiburg)
Hugues Meyer (U of Saarland)
Tanja Schilling (U of Freiburg)