Mechanical memory effects in solid-like polymers

Sara Jabbari-Farouji (U of Amsterdam)

Jun 25. 2021, 15:00 — 15:30

Disordered solids that have undergone a plastic deformation in one direction, "remember" that direction also when relaxed back to the state of zero-stress. This  mechanical memory effect is well visible in the so-called Bauschinger effect:  materials that have experienced a plastic strain exhibit a softer stress response under reverse loading as  compared with reloading in the same direction. The origin of the Bauschinger  effect in solid-like polymers remains elusive and it is not clear what is the order parameter that is responsible for this memory.  We perform  large-scale molecular dynamic simulations of glassy and semicrystalline polymers of a coarse-grained model to shed light into the structural origin of the mechanical memory.  We find that the  degree of chain orientation and stretch are correlated to the cumulative strain provide  a good measure of mechanical memory in solid-like polymers. 

Further Information
Venue:
ESI Boltzmann Lecture Hall
Associated Event:
Memory Effects in Dynamical Processes: Theory and Computational Implementation (Online Workshop)
Organizer(s):
Christoph Dellago (U of Vienna)
Anja Kuhnhold (U of Freiburg)
Hugues Meyer (U of Saarland)
Tanja Schilling (U of Freiburg)